Institute of Atomic and molecular Sciences, Academia Sinica

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Dr. Jim Jr-Min Lin (Chemical Dynamics and Spectroscopy)

Atmospheric Chemistry and Reaction Dynamics Laboratory

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Basic Information

Honors, Awards, and Recognitions

Selected Publications

Research Works

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Selected Publications

J. J. Lin, J.-G. Zhou, W.-C. Hsu, and K. Liu, Application of time-sliced ion velocity imaging to crossed molecular beam experiments, Rev. Sci. Instrum. 74, 2495 (2003).
J.-G. Zhou, J. J. Lin, W.-C. Hsu, S.-C. Pu and K. Liu, Crossed-beam scattering of F + CD₄ ® DF + CD₃(nNK): the integral cross sections, J. Chem. Phys. 119, 2538 (2003).
J. J. Lin, J.-G. Zhou, W.-C. Hsu, and K. Liu, State-specific correlation of coincident product pairs in the F + CD₄ reaction, Science, 300, 966 (2003).
J.-G. Zhou, J. J. Lin, W.-C. Hsu, and K. Liu, Insights into dynamics of the F + CD₄ reaction via product pair-correlation, J. Chem. Phys. 119, 4997 (2003).
J.-G. Zhou, J. J. Lin, and K. Liu, Mode-correlated product pairs in the F + CHD₃ ® DF + CHD₂ reaction, J. Chem. Phys. 119, 8289 (2003).
M. J. Perri, A. L. Van Wyngarden, K. A. Boering, J. J. Lin, and Y. T. Lee, Dynamics of the O(¹D) + CO₂ oxygen isotope exchange reaction, J. Chem. Phys. 119, 8213 (2003).
W.-C. Hsu, J. J. Lin, K. Liu, M. Wu and D. H. Parker, Imaging the pair-correlated excitation functions: The F + CH₄ ® HF(v’) + CH₃(v=0) reaction, J. Chem. Phys. 120, 117 (2004).
W.-C. Hsu, J. J. Lin, and K. Liu, Reactive resonance in a polyatomic reaction, Phys. Rev. Lett. 92, 103201 (2004).
J.-G. Zhou, W.-C. Shiu, J. J. Lin, and K. Liu, Rotationally selected product pair correlation in F + CD₄ ® DF(v’) + CD₃(v= 0,N), J. Chem. Phys. 120, 5863 (2004).
M. J. Perri, A. L. Van Wyngarden, J. J. Lin, Y. T. Lee, and K. A. Boering, Energy dependence of oxygen isotope exchange and quenching in the O(¹D) + CO₂ reaction: A crossed molecular beam study, J. Phys. Chem. A 108, 7995 (2004).
J.-G. Zhou, J. J. Lin, B.-L. Zhang, and K. Liu, On the Cl*(²P_1/2) reactivity and the effect of bend excitation in the Cl + CH₄/CD₄ reactions, J. Phys. Chem. A 108, 7832 (2004).
J.-G. Zhou, J. J. Lin, and K. Liu, Observation of a reactive resonance in the integral cross section of a six-atom reaction: F + CHD₃, J. Chem. Phys. 121, 813 (2004).
S. H. Lee, J. J. Lin, and Y. T. Lee, Selective ionization of photofragments using tunable radiation from a synchrotron, J. Ele. Spectr. and Rel. Phen. 144-147, 135 (2005).
B.-L. Zhang, W.-C. Shiu, J. J. Lin, and K. Liu, Mode correlation of product pairs in the reaction OH+CD₄ ® HOD+CD₃, J. Chem. Phys. 122, 131102 (2005).
P. C. Samartzis, J. J. Lin, T.-T. Ching, C. Chaudhuri, Y. T. Lee, S.-H. Lee, and A. M. Wodtke, Two photoionization thresholds of N₃ produced by ClN₃ photodissociation at 248 nm: Further evidence for cyclic N₃, J. Chem. Phys. 123, 051101 (2005).
L. R. McCunn, K. C. Lau, M. J. Krisch, L. J. Butler, J.-W. Tsung and J. J. Lin, Unimolecular Dissociation of the CH₃OCO Radical: An intermediate in the CH₃O + CO Reaction, J. Phys. Chem. A 110, 1625 (2006).
J.-G. Zhou, W.-C. Shiu, J. J. Lin, and K. Liu, Rotationally selected product pair correlation: F + CD₄ ® DF(v’) + CD₃(v₂= 0 and 2, N), J. Chem. Phys. 124, 104309 (2006).
Y.-J. Lu, C.-W. Liang, and J. J. Lin, Crossed molecular beam studies on the reaction dynamics of O(¹D) + N₂O, J. Chem. Phys. 125, 133121 (2006).
L. R. McCunn, B. L. FitzPatrick, M. J. Krisch, L. J. Butler, C.-W. Liang, and J. J. Lin, Unimolecular dissociation of the propargyl radical intermediate of the CH+C₂H₂ and C+C₂H₃ reactions, J. Chem. Phys. 125, 133306 (2006).
S.-J. Tang, Y.-C. Chou, J. J. Lin, and Y.-C. Hsu, The bending vibrational levels of the acetylene cation: A case study of the Renner-Teller effect in a molecule with two degenerate bending vibrations, J. Chem. Phys. 125, 133201 (2006).
C. Larson, Y. Ji, P. Samartzis, A. M. Wodtke, S.-H. Lee, J. J. Lin, C. Chaudhuri, and T.-T. Ching, Collision-free photochemistry of methylazide: Observation of unimolecular decomposition of singlet methylnitrene, J. Chem. Phys. 125, 133302 (2006).
Y. Ji, P. Bobadova-Parvanova, C. Larson, P. C. Samartzis, K. Morokuma, J. J. Lin, T.-T. Ching, C. Chaudhuri, S.-H. Lee, and A. M. Wodtke, The heat of formation of chlorine-isocyanate and the relative stability of isoelectronic molecules: An experimental and theoretical study, J. Chem. Phys. 124, 241106 (2006).
A. Van Wyngarden, K. Mar, K. Boering, J. J. Lin, Y. T. Lee, S. Y. Lin, H. Guo, G. Lendvay, Non-statistical Behavior of Reactive Scattering in the ¹⁸O+³²O₂ Isotope Exchange Reaction, J. Am. Chem. Soc. 129, 2866 (2007).
Peter C. Samartzis, Jim Jr-Min Lin, Tao-Tsung Ching, Chanchal Chaudhuri, Shih-Huang Lee, and Alec M. Wodtke, The simplest all-nitrogen ring: Photolytically filling the cyclic-N3 well, J. Chem. Phys. 126, 041101 (2007).
B. L. FitzPatrick, M. Maienschein-Cline, L. J. Butler, S. -H. Lee, and J. J. Lin, Determining the Partial Photoionization Cross Sections of Ethyl Radicals, J. Phys. Chem. A 111, 12417 (2007).
Yu-Ju Lu, Lance Lee, Jun-Wei Pan, Henryk A. Witek and Jim Jr-Min Lin, Dynamics of the F₂ + CH₃SCH₃ reaction -- A molecule-molecule reaction without entrance barrier, J. Chem. Phys. 127, 101101 (2007) (Communication).
Yu-Ju Lu, Lance Lee, Jun-Wei Pan, Tingxian Xie, Henryk A. Witek and Jim Jr-Min Lin, Barrierless reactions between two closed-shell molecules. I. Dynamics of F₂+CH₃SCH₃ reaction, J. Chem. Phys. 128, 104317 (2008).
Y.-J. Lu, T. Xie, J.-W. Fang, H.-C. Shao and J. J. Lin, Dynamics of the F₂ reaction with the simplest p-bonding molecule, J. Chem. Phys. 128, 184302 (2008).
H.-F. Chen , C.-W. Liang , J. J. Lin , J. F. Ogilvie , Z. F. Xu , M. C. Lin, and Y.-P. Lee, Dynamics of Reactions O(¹D) + C₆H₆ and C₆D₆, J. Chem. Phys. 129, 174303 (2008).
I-C. Lu , W.-K. Chen , C. Chaudhuri , W.-J. Huang , J. J. Lin and S.-H. Lee, Exploring the dynamics of reaction N + SiH₄ via crossed molecular-beam experiments and quantum-chemical calculations, J. Chem. Phys. 129, 174304 (2008).
Benjamin L. FitzPatrick, Kai-Chung Lau, Laurie J. Butler, Shih-Huang Lee, and Jim Jr-Min Lin, Investigation of the O+allyl addition/elimination reaction pathways from the OCH₂CHCH₂ radical intermediate, J. Chem. Phys. 129, 084301 (2008).
H.-C. Shao, T. Xie, Y.-J. Lu, C.-H. Chang, J.-W. Pan, and J. J. Lin, Barrierless Reactions between Two Closed-shell Molecules. II. Dynamics of F₂ + CH₃SSCH₃ Reaction, J. Chem. Phys. 130, 014301 (2009).
Jing-Wen Fang, Tingxian Xie, Hsueh-Ying Chen, Yu-Ju Lu, Yuan T. Lee and Jim J. Lin, Dynamics of the F₂ reaction with propene: the effect of methyl substitution, J. Phys. Chem. A 113, 4381 (2009).
H.-Y. Chen, C.-Y. Lien, W.-Y. Lin,. Y. T. Lee, and J. J. Lin, UV Absorption Cross Sections of ClOOCl Are Consistent with Ozone Degradation Models, Science 324, 781 (2009).
Chien-Yu Lien, Wei-Yen Lin, Hsueh-Ying Chen, Wen-Tsung Huang, Bing Jin, I-Cheng Chen, and Jim J. Lin, Photodissociation cross sections of ClOOCl at 248.4 and 266 nm, J. Chem. Phys. 131, 174301 (2009).
Bing Jin, I-Cheng Chen, Wen-Tsung Huang, Chien-Yu Lien, Nikhil Guchhait, and Jim J. Lin, Photodissociation Cross Section of ClOOCl at 330 nm, J. Phys. Chem. A, 114, 4791 (2010).
Wen-Tsung Huang, Andrew F. Chen, I-Cheng Chen, Chen-Hsun Tsai and Jim Jr-Min Lin, Photodissociation dynamics of ClOOCl at 248.4 and 308.4 nm, Phys. Chem. Chem. Phys., 13, 8195-8203 (2011).
Jim J. Lin, Andrew F Chen, and Yuan T. Lee, UV Photolysis of ClOOCl and the Ozone Hole, Chem. Asian J., 6, 1664 (2011).
Zhi-Qiang Li, Chen-Hsun Tsai, Andrew F Chen, Yu-Ju Lu, Jim J. Lin, Double methyl substitution in simple alkenes leads to low-barrier reactions towards molecular fluorine, Chem. Phys. Lett., 510, 42-47 (2011).
I-Cheng Chen, Andrew F Chen, Wen-Tsung Huang, Kaito Takahashi and Jim J. Lin, Photolysis Cross Section of Ozone Dimer, Chem. Asian J., 6, 2925-2930 (2011).
Jim J. Lin, Dynamics of Reactions between Two Closed-shell Molecules, Phys. Chem. Chem. Phys., 13, 19206-19213 (2011).
Bing Jin, Man-Nung Su, and Jim J. Lin, Does Ozone-Water Complex Produce Additional OH Radicals in the Atmosphere? J. Phys. Chem. A, 116, 12082-12088 (2012).
Man-Nung Su and Jim Jr-Min Lin, A transient absorption spectrometer using an ultra bright laser-driven light source, Rev. Sci. Instrum. 84 , 086106 (2013).
Man-Nung Su and Jim Jr-Min Lin, Formation of NO₃ in the Photolysis of N₂O₅, GSTF Journal of Chemical Sciences (JChem) (ISSN: 2339-5060) 2013, 1, 52-57. (DOI: 10.5176/2339-5060_1.1.6)
Wei-Lun Ting, Ying-Hsuan Chen, Wen Chao, Mica C. Smith and Jim J. Lin, The UV Absorption Spectrum of the Simplest Criegee Intermediate CH₂OO Phys. Chem. Chem. Phys., 16, 10438-10443 (2014).
Mica C. Smith, Wei-Lun Ting, Chun-Hung Chang, Kaito Takahashi, Kristie A. Boering, and Jim Jr-Min Lin, UV absorption spectrum of the C2 Criegee intermediate CH₃CHOO, J. Chem. Phys., 141, 074302 (2014).
Wei-Lun Ting, Chun-Hung Chang, Yu-Fang Lee, Hiroyuki Matsui, Yuan-Pern Lee and Jim Jr-Min Lin., Detailed mechanism of the CH₂I+O₂ reaction: Yield and self-reaction of the simplest Criegee intermediate CH₂OO, J. Chem. Phys., 141, 104308 (2014).
Wen Chao, Jun-Ting Hsieh, Chun-Hung Chang, Jim Jr-Min Lin, Direct kinetic measurement of the reaction of the simplest Criegee intermediate with water vapor, Science 347, 751 (2015).
Mica C. Smith, Chun-Hung Chang, Wen Chao, Liang-Chun Lin, Kaito Takahashi, Kristie A. Boering and Jim Jr-Min Lin, Strong Negative Temperature Dependence of the Simplest Criegee Intermediate CH₂OO Reaction with Water Dimer, J. Phys. Chem. Lett., 6, 2708-2713 (2015).
Hao-Li Huang, Wen Chao, and Jim Jr-Min Lin, Kinetics of a Criegee intermediate that would survive high humidity and may oxidize atmospheric SO₂, Proc. Natl. Acad. Sci. USA, 112 (35), 10857–10862 (2015). doi/10.1073/pnas.1513149112.
Lauren A. Garofalo, Mica C. Smith, Paul J. Dagdigian, Jacek Kłos, Millard H. Alexander, Kristie A. Boering and Jim Jr-Min Lin, Electronic quenching of O(¹D) by Xe: Oscillations in the product angular distribution and their dependence on collision energy, J. Chem. Phys. 143, 054307 (2015).
Mica C. Smith, Wen Chao, Kaito Takahashi, Kristie A. Boering, and Jim Jr-Min Lin*, Unimolecular Decomposition Rate of the Criegee Intermediate (CH₃)₂COO Measured Directly with UV Absorption Spectroscopy, J. Phys. Chem. A, 120, 4789–4798 (2016), DOI: 10.1021/acs.jpca.5b12124
Yuan-Pin Chang, Chun-Hung Chang, Kaito Takahashi, Jim Jr-Min Lin, Absolute UV absorption cross sections of dimethyl substituted Criegee intermediate (CH₃)₂COO, Chem. Phys. Lett. 653, 155-160 (2016). https://doi.org/10.1016/j.cplett.2016.04.082
Liang-Chun Lin, Wen Chao, Chun-Hung Chang, Kaito Takahashi* and Jim Jr-Min Lin*, Temperature dependence of the reaction of anti-CH₃CHOO with water vapor, Phys. Chem. Chem. Phys., 18, 28189-28197 (2016). doi: 10.1039/C6CP05171E
Mica C. Smith, Wen Chao, Manoj Kumar, Joseph S. Francisco, Kaito Takahashi*, and Jim Jr-Min Lin*, Temperature-Dependent Rate Coefficients for the Reaction of CH₂OO with Hydrogen Sulfide, J. Phys. Chem. A, 121, 938–945 (2017). doi:10.1021/acs.jpca.6b12303
Allen Wei-Lun Ting, Jim Jr-Min Lin*, UV Spectrum of the Simplest Deuterated Criegee Intermediate CD₂OO, J. Chin. Chem. Soc. 64, 360–368 (2017). doi:10.1002/jccs.201700049
Y. P. Chang, A. J. Merer, H. H. Chang, L. J. Chang, W. Chao, and J. J.-M. Lin, High resolution quantum cascade laser spectroscopy of the simplest Criegee intermediate, CH₂OO, between 1273 cm⁻¹ and 1290 cm⁻¹, J. Chem. Phys., 146, 244302 (2017). DOI: 10.1063/1.4986536
Jim Jr-Min Lin*, and Wen Chao, Structure-dependent reactivity of Criegee intermediates studies with spectroscopic methods, Chem. Soc. Rev., 46, 7483-7497 (2017); DOI:10.1039/c7cs00336f.
Yuan-Pin Chang,* Hsun-Hui Chang and Jim Jr-Min Lin, Kinetics of the simplest Criegee intermediate reaction with ozone studied using a mid-infrared quantum cascade laser spectrometer, Phys. Chem. Chem. Phys., 20, 97-102 (2018). DOI: 10.1039/c7cp06653h
Yen-Hsiu Lin, Kaito Takahashi, and Jim Jr-Min Lin*, The Reactivity of Criegee Intermediates towards Carbon Dioxide, J. Phys. Chem. Lett., 9, 184−188 (2018). DOI: 10.1021/acs.jpclett.7b03154
Yuan-Pin Chang,* Yu-Lin Li, Meng-Ling Liu, Ting-Chun Ou, and Jim Jr-Min Lin, Absolute Infrared Absorption Cross Section of the Simplest Criegee Intermediate Near 1285.7 cm^–1, J. Phys. Chem. A, 122 (45), 8874–8881 (2018). DOI: 10.1021/acs.jpca.8b06759
Yen-Hsiu Lin, Cangtao Yin, Wei-Hong Lin, Yu-Lin Li, Kaito Takahashi,* and Jim Jr-Min Lin*, Criegee Intermediate Reaction with Alcohol Is Enhanced by a Single Water Molecule, J. Phys. Chem. Lett. 9, 7040−7044 (2018). DOI: 10.1021/acs.jpclett.8b03349
Wen Chao, Cangtao Yin, Yu-Lin Li, Kaito Takahashi,* and Jim Jr-Min Lin*, Synergy of Water and Ammonia Hydrogen Bonding in a Gas-Phase Reaction, J. Phys. Chem. A 123, 1337 (2019 Jan.). DOI: 10.1021/acs.jpca.9b00672.
Wen Chao, Jim Jr-Min Lin, Kaito Takahashi, Alexandre Tomas, Lu Yu, Yoshizumi Kajii, Sebastien Batut, Coralie Schoemaecker, and Christa Fittschen*, Water Vapor Does Not Catalyze the Reaction between Methanol and OH Radicals, Angew. Chem. Int. Ed. 58, 5013 –5017 (2019).
Wen Chao, Yen-Hsiu Lin, Cangtao Yin, Wei-Hong Lin, Kaito Takahashi* and Jim Jr-Min Lin* (2019, Jun). Temperature and isotope effects in the reaction of CH₃CHOO with methanol, Phys. Chem. Chem. Phys., 21, 13633-13640.
Wen Chao, Cangtao Yin, Kaito Takahashi and Jim Jr-Min Lin, Hydrogen-Bonding Mediated Reactions of Criegee Intermediates in the Gas Phase ― The Competition between Bimolecular and Termolecular Reactions and the Catalytic Role of Water, J. Phys. Chem. A 123, 8336-8348 (2019 Sept.) (Feature Article); DOI: 10.1021/acs.jpca.9b07117
Wen Chao, Cangtao Yin, Kaito Takahashi and Jim Jr-Min Lin, Effects of Water Vapor on the Reaction of CH₂OO with NH₃, Phys. Chem. Chem. Phys., 21, 22589-22597 (2019 Sept.); DOI: 10.1039/C9CP04682H
Yu-Lin Li, Yen-Hsiu Lin, Cangtao Yin, Kaito Takahashi*, Che-Yu Chiang, Yuan-Pin Chang*, Jim Jr-Min Lin, Temperature-Dependent Rate Coefficient for the Reaction of CH₃SH with the Simplest Criegee Intermediate, J. Phys. Chem. A 2019, 123, 19, 4096-4103. https://doi.org/10.1021/acs.jpca.8b12553
Yu-Lin Li, Mei-Tsan Kuo and Jim Jr-Min Lin, Unimolecular decomposition rates of a methyl-substituted Criegee intermediate syn-CH₃CHOO, RSC Advances, 2020, 10, 8518 – 8524. DOI: 10.1039/d0ra01406k
R. L. Caravan, M. F. Vansco, K. Au, M. A. H. Khan, Y.-L. Li, F. A. F. Winiberg, K. Zuraski, Y.-H. Lin, W. Chao, N. Trongsiriwat, P. J. Walsh, D. L. Osborn, C. J. Percival, J. J.-M. Lin, D. E. Shallcross, L. Sheps, S. J. Klippenstein, C. A. Taatjes and M. I. Lester, First direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate with implications for aerosol formation, Proc. Natl. Acad. Sci. U.S.A., 2020, www.pnas.org/cgi/doi/10.1073/pnas.1916711117
Yen-Hsiu Lin, Yu-Lin Li, Wen Chao, Kaito Takahashi and Jim Jr-Min Lin, The role of the iodine-atom adduct in the synthesis and kinetics of methyl vinyl ketone oxide—a resonance-stabilized Criegee intermediate, Phys. Chem. Chem. Phys., 2020, 22, 13603-13612; DOI:10.1039/d0cp02085k
Yu‐Lin Li, Chun‐Yu Lin, Yen‐Hsiu Lin, and Jim Jr‐Min Lin, Temperature‐dependent kinetics of the simplest Criegee intermediate reaction with dimethyl sulfoxide, J. Chin. Chem. Soc. 67, 1563–1570 (2020); DOI: 10.1002/jccs.202000206
Mei‐Tsan Kuo, Kaito Takahashi, and Jim Jr‐Min Lin, Reactions of Criegee Intermediates are Enhanced by Hydrogen‐Atom Relay Through Molecular Design, ChemPhysChem, 21, 2056–2059 (2020); https://doi.org/10.1002/cphc.202000585
Mei-Tsan Kuo, Isabelle Weber, Christa Fittschen, Luc Vereecken, Jim Jr-Min Lin, Kinetics of dimethyl sulfide (DMS) reactions with isoprene-derived Criegee intermediates studied with direct UV absorption, Atmos. Chem. Phys. 20, 12983–12993 (2020); https://doi.org/10.5194/acp-20-12983-2020
Yen-Hsiu Lin, Chung-Hsin Yang, Kaito Takahashi and Jim Jr-Min Lin*, Kinetics of Unimolecular Decay of Methyl Vinyl Ketone Oxide, an Isoprene-Derived Criegee Intermediate, under Atmospherically Relevant Conditions, J. Phys. Chem. A 124, 45, 9375–9381 (2020); https://dx.doi.org/10.1021/acs.jpca.0c07928
Yen-Hsiu Lin, Cangtao Yin, Kaito Takahashi, and Jim Jr-Min Lin, Surprisingly long lifetime of methacrolein oxide, an isoprene derived Criegee intermediate, under humid conditions, Commun. Chem. 4, 12 (2021); https://doi.org/10.1038/s42004-021-00451-z (Feb 2021)
Mei-Tsan Kuo, Jie-Ning Yang, Jim Jr-Min Lin*, and Kaito Takahashi*, Substituent Effect in the Reactions between Criegee Intermediates and 3-Aminopropanol, J. Phys. Chem. A 2021, 125, 30, 6580–6590; https://doi.org/10.1021/acs.jpca.1c03737 (July 2021)
Yen-Hsiu Lin, Jim Jr-Min Lin*, A new approach to determine the absolute photodissociation cross section of molecules in a cell, J. Chin. Chem. Soc. 2022, 69, 152-159; https://doi.org/10.1002/jccs.202100336 (Sep 2021)
Yen-Hsiu Lin, Kaito Takahashi* and Jim Jr-Min Lin*, Absolute photodissociation cross sections of thermalized methyl vinyl ketone oxide and methacrolein oxide, Phys. Chem. Chem. Phys., 2022; DOI https://doi.org/10.1039/D2CP00476C (Apr 2022)
Yen-Hsiu Lin, Yen-Ju Wu and Jim Jr-Min Lin*, Building an oxidation reactor in Taiwan: From volatile organic compounds to secondary organic aerosols, J. Chin. Chem. Soc. (2022) DOI: 10.1002/jccs.202200470.
Guan-Jie Luo, Pei-Hsuan Wu, Ming-Le Lin, Fang-Fei Chou, and Jim Jr-Min Lin*, Kinetics of the Color-Fading Reaction of Phenolphthalein in Alkaline Solution Studied with a Simple and Economical Device, J. Chem. Edu., 2023, 100, 11, 4298-4306. DOI: 10.1021/acs.jchemed.3c00390.
Yen-Ju Wu, Kaito Takahashi and Jim Jr-Min Lin, Kinetics of the Simplest Criegee Intermediate Reaction with Water Vapor: Revisit and Isotope Effect, J. Phys. Chem. A, 2023, 127, 8059. DOI: 10.1021/acs.jpca.3c03418

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Institute of Atomic and Molecular Sciences Academia Sinica

Dr. Jim Jr-Min Lin (Chemical Dynamics and Spectroscopy)