|
XueMing
Yang
Associate Research Fellow,IAMS Adjunct Associate Professor,NTHU Institute of Atomic and Molecular
Sciences
Tel: 886-2-23668278 (office),
E-mail:xmyang@po.iams.sinica.edu.tw |
---|
Born: October 11, 1962, Zhejiang Province,
China
Married: May 1988 in Santa Barbara, California, USA
Citizenship: USA
.Education
1991 Ph. D. in Chemistry, University of California,
Santa Barbara, USA
1985 M. Sc. in Chemical Physics, Dalian Institute of Chemical Physics,
Chinese Academy of Sciences, China
1982 B. Sc. in Physics, Zhejiang Normal University, Zhejiang, China
.Professional Experience
Adjunct Associate Professor, Department of Chemistry, National Tsing Hua University, 8/1/1999-present
Associate Research Fellow, Institute of Atomic and Molecular Sciences,
Academia Sinica,
12/1995-present.
Visiting Research Associate, Lawrence Berkeley National Laboratories, University
of California,
5/93-11/95 (Advisor: Prof. Yuan T. Lee)
Post Doctoral Research Associate, Princeton University, 9/91-5/93 (Advisor: Prof. Giacinto Scoles)
Research Assistant, Department of Chemistry, University of California,
Santa Barbara, 1/89-8/91
(Advisor: Prof. Alec M. Wodtke)
.Research Interest
Dynamics of unimolecular photodissociation
and bimolecular reactions using universal crossed
experimental techniques based on electron impact ionization and VUV (synchrotron
& laser based)
photoionization.
State-to-state chemistry of unimolecular and bimolecular reactions using
the H atom Rydberg
¨tagging〃 TOF technique.
. Honors and Awards
Graduate Thesis Award, Zhejiang Normal
University, 1982.
UC Regents Fellowship, U.C. Santa Barbara, 1989-1990.
NSC Outstanding Young Investigator Outstanding, 1998 & 1999.
Young Scientist Award, Academia Sinica, 1999.
Outstanding Young Chemist Award, Chinese Chemical Society, Taipei, 1999.
Best Research Article Award in JCCS, 1999.
JILA Visiting Fellowship, University of Colorado, Boulder, 2000
NSC Outstanding Investigator,1999-2000
.Publications
(1) X. Yang, Z. Y. Shen, Q. S. Zhu,
C. H. Zhang, Infrared diode Laser spectroscopy of ?4 band of
acetonitrile, Chinese Lasers, 13,351(1986).
(2) X. Yang, A. M. Wodtke, Potential energy surface and transition dipole
moment function of
Schumann-Runge near X state dissociation, J. Chem. Phys. 90, 7114(1989).
(3) X. Yang, C. A. Rogaski, A. M. Wodtke, Rotational structure of highly
vibrationally excited HCN,
J. Chem. Phys. 92, 2111(1990).
(4) X. Yang, A. M. Wodtke, Efficient state preparation of NO at very high
vibrational energy, J. Chem.
Phys. 92,116(1990).
(5) H. Petek, D. J. Nesbitt, J. C. Owrustsky, G. S. Gudemann, X. Yang,
D. O. Harris, C. B. Moore, and
R. J. Saykally, A study of the structure and dynamics of the hydronium
ion by high resolution infrared
spectroscopy III: the ?3 band of D3O+, J. Chem. Phys. 92,3257(1990).
(6) X. Yang, E. H. Kim, A. M. Wodtke, The vibrational quantum number dependence
of the collissional
lifetime of nitric oxide self-relaxation up to ?=25, J. Chem. Phys.
93,4483(1990).
(7) X. Yang, C. A. Rogaski and A. M. Wodtke, Vibrational structure of HCN
between 9000 and
19000 cm-1, J. Opt. Soc. Am. B7, 1835(1990).
(8) X. Yang, C. A. Rogaski, E. H. Kim, D. McGuire, A. M. Wodtke, Vibrational
spectroscopy with tunable
ArF laser, Lamda Physik Highlights 24,1 (1990).
(9) X. Yang, L. Huwel and A. M. Wodtke, Direct observation of orbit-rotation
predissociation in the O3
Schumann-runge system, J. Chem. Phys. 94,2469 (1991).
(10) Xueming Yang, Spectroscopy and Collisional Dynamics of Highly
Vibrationally Excited Molecules,
Ph.D. Thesis, University of California, Santa Barbara, 1991.
(11) X. Yang and A. M. Wodtke, Reply to comment on Rotational structure
of highly vibrationally excited
HCN, J. Chem. Phys. 93,3723(1990).
(12) X. Yang, D. McGuire, A. M. Wodtke, Efficient state-specific preparation
of very highly vibrationally
excited 15N18O, J. Mol. Spectrosc. 154, 362(1992).
(13) X. Yang, E. H. Kim, A. M. Wodtke, Vibrational energy transfer of very
highly vibrationally excited
NO molecules, J. Chem. Phys. 96,5111(1992).
(14) X. Yang, A. M. Wodtke, Rotational and spin-orbit state-to-state energy
transfer of very highly
vibrationally excited NO, J. Chem. Phys.96,5123(1992).
(15) D. Jonas, X. Yang, A. M. Wodtke, Axis-switching transitions and the
stimulated emission pumping
spectrum of HCN, J. Chem. Phys. 97, 2284(1992).
(16) X. Yang, A. M. Wodtke, Vibrational energy transfer of highly vibrationally
excited NO, SPIE
Conference Proceedings, Los Angeles, California,1992.
(17) X. Yang, E. R. Th. Kerstel, G. Scoles, Intramolecular coupling enhanced
predissociation in
HCCCN-HCN, J. Chem. Phys. 98,2727(1993).
(18) J. Gambogi, K. K. Lehmann,B. H. Pate,G. Scoles,and X. Yang, Intramolecular
vibrational relaxation
rate of (CF3)3CCCH, J. Chem. Phys. 98,1748(1993).
(19) X. Yang, R. Z. Pearson and G. Scoles, High resolution IR studies of
the OC-HCCCN complex,
Chem. Phys. Lett. 204,146(1993).
(20) E. R. Th. Kerstel, G. Scoles and X. Yang, Predissociation and structure
of (HCCCN)2: a high
resolution IR study, J. Chem. Phys., 99(2), 876-84(1993).
(21) X. Yang,E. R. Th. Kersteel, and G. Scoles, High resolution IR spectroscopy
of the HCCCN-HX
complexes: X=CN,F, J. Chem. Phys., 99(1), 760-1(1993).
(22) X. Yang, A. M. Wodtke, Controlling the quantum numbers in chemical
reaction: reactivity and energy
transfer of highly vibrationally excited molecules, International reviews
in Physical Chemistry 12,
123(1993).
(23) X. Yang, J. M. Price, J. A. Mack, C. G. Morgan, C. A. Rogaski, D.
McGuire, E. H. Kim,
A. M. Wodtke, Stimulated emission pumping study of energy transfer in highly
vibrationally excited
molecules, J. Phys. Chem., feature article, edited by M. El-Sayed,93, 3944(1993).
(24) E. R. Th. Kerstel, K. K. Lehmann, J. E. Gambogi, X.Yang and G. Scoles,
The v1 vibrational
predissociation lifetime of (HCN)2 determined from upper state microwave-infrared
double resonance
measurements, J. Chem. Phys., 99(11), 8559-70(1993).
(25) E. R. Th. Kerstel, X. Yang, and G. Scoles, High resolution IR studies
of HCN-BF3 and HCCCN-BF3,
J. Chem. Phys. 101(4), 3298-300(1994).
(26) J. M. Price, J. A. Mack, G. von Heldon, X. Yang, and A. M. Wodtke,The
structure of acetaldehyde
in its first excited single state: experiment and theory, J.
Phys. Chem. 98, 1791(1994).
(27) D. Stranges, X. Yang, J. Chesko, and A. Suits, Ozone photodissociation
at 193 nm, J. Chem. Phys.
102(15), 6067-77(1995).
(28) X. Yang, E. R. Th. Kerstel, G. Scoles, R. J. Bemish and R. E. Miller,
IR spectroscopic studies of the
HCCCN trimer and high polymers in a molecular beam, J. Chem. Phys. 103,
8828(1995).
(29) X. Yang, J. M. Price, J. A. Mack, C. G. Morgan and A. M. Wodtke, How
does collisional energy
transfer depend on vibrational excitation? , Chapter 17, Molecular Dynamics
and Spectroscopy by
Stimulated Emission Pumping, edited by C. Ng, R. W. Field,H. L. Dai, World
Scientific, 1995.
(30) D. Jonas, C. A. Rogaski, A. M. Wodtke and X. Yang, High Resolution
Spectroscopy of Chemical
Isomerization: Stimulated Emission Pumping, Chapter 14, Molecular
Dynamics and Spectroscopy by
Stimulated Emission Pumping, edited by C. NG,R. W. Field,H. L. Dai, World
Scientific, 1995.
(31) X. Yang, A. M. Wodtke, Collisional dynamics of highly vibrationally
excited molecules,"Vibrational
Energy Transfer Involving Large and Small Molecules,Vol. 2, Advances in
Chemical Kinetics and
Dynamics,edited by J. R. Barker, 105(1995).
(32) A. G. Suits, P. Heimann, X. Yang, M. Evans, C. W. Hsu, K. T. Lu, Y.
T. Lee, and A. H. Kung, A
differentially pumped harmonic filter on the chemical dynamics beamline
at the Advanced Light
Sourcve, Rev. Sci. Instrum., 66, 4841(1995).
(33) J. Gambogi, E. R. Th. Kerstel, K. K. Lehmann, G. Scoles and X. Yang,
Spectroscopic studies of the
highly vibrationally excited HCCCCH Molecule, Chem. Phys. 190(2,3), 191-205(1995).
(34) J. Gambogi, E. R. Th. Kerstel, X. M. Yang, K. K. Lehmann and G. Scoles,
High Resolution spectrum
of the 3v1 band of cyanoacetylene, J. Mol. Spectrosc. 175, 198-202(1996).
(35) X. Yang, R. Z. Pearson, and G. Scoles, A high resolution IR study
of the HCN-HCCCCH and
HCCCN-HCCH complexes, J. Chem. Phys. 105, 10725-10733(1996).
(36) P. A. Heimann, M. Koike, C. W. Hsu, M. Evans, C. Y. Ng, D. Blank,
X. M. Yang, C. Flaim,
A. G. Suits and Y. T. Lee, Performance of the VUV high resolution and high
flux beamline for
chemical dynamics studies at the Advanced Light Source, Proceedings of
SPIE, Vol. 2856(1996).
(37) X. Yang, E. R. Th. Kerstel and G. Scoles, High resolution IR studies
of HCCCN complexes with
quadrupolar molecules: N2,CO2, J. Mol. Spectrosc. 180, 1(1996).
(38) X. Yang, D. A. Blank, J. Lin, P. A. Heimann, A. M. Wodtke, Y. T. Lee
and A. G. Suits, Chemical
reaction dynamics using the advanced light source. Synchrotron Radiation
Techniques in Industrial,
Chemical, and Material Science, Edited by Dimico et al., Plenum Press,
New York, 1996, pp119-128.
(39) X. Yang, J. Lin and Y. T. Lee, New VUV light sources for chemical
dynamics research, Lamda
Physik Highlights, 50, 4(1996). (IAMS)
(40) P. R. Bloch, R. E. Miller, X. Yang, G. Scoles, The Ar-Diacetylene
Complex: An example of
distributed interactions and transferable potentials, J. Chem. Phys. 105(23),
10171-10177(1996).
(41) X. Yang, D. A. Blank, J. Lin, A. G. Suits, Y. T. Lee and A. M. Wodtke,
A universal crossed molecular
beam apparatus with synchrotron photo-ionization mass spectrometric product
detection, Review of
Scientific Instruments 68, 3317(1997).
(42) P. A. Heimann, M. Koike, C. W. Hsu, D. Blank, X. M. Yang, A. G. Suits,
Y. T. Lee, M. Evans,
C. Y. Ng, C. Flaim, H. A. Padmore, Performance of the vacuum unltraviolet
high resolution and high
flux beamline for chemical dynamics studies at the Advanced Light Source,
Review of Scientific
Instruments, 68, 1945(1997).
(43) A. M. Mebel, S. H. Lin, X. M. Yang and Y. T. Lee, Theoretical study
on the mechanism of the
dissociation of benzene: The C5H3 + CH3 product channel, J. Phys. Chem.
101, 6781(1997). (IAMS)
(44) J. J. Lin, D. W. Hwang, Y. T. Lee, and X. Yang, A new crossed molecular
beam apparatus,
Instruments Today, Vol. 19(2), 40(1997). (IAMS)
(45) J. J. Lin, D. W. Hwang, Y. T. Lee and X. Yang, VUV photodissociation
dynamics of OClO: binary and
triple dissociation, Laser Techniques for State-Selected and State-to-State
Chemistry IV, Proceedings
of SPIE, Vol. 3271, 15(1998). (IAMS)
(46) J. J. Lin, D. W. Hwang, S. Harich, Y. T. Lee and X. Yang, A new low
background crossed molecular
beam apparatus: low background detection of H2, Rev. Sci. Instrum. 69,
1642 (1998). (IAMS)
(47) J. J. Lin, D. W. Hwang, Y. T. Lee, and X. Yang, On the experimental
observation of anisotropy
mixing in the O2 photodissociation, J. Chem. Phys. 109, 1758(1998). (IAMS)
(48) J. J. Lin, D. W. Hwang, Y. T. Lee and X. Yang, Photodissociation studies
of OClO at 157 nm
J. Chem. Phys. 108, 10061(1998). (IAMS)
(49) A. H. H. Chang, A. M. Mebel, X. Yang, S. H. Lin and Y. T. Lee,
Ab inito calculations of potential
energy surface and rate constants for ethylene photodissociation at 193
and 157 nm, Chem. Phys. Lett.
287, 301(1998). (IAMS)
(50) A. H. H. Chang, A. M. Mebel, X. Yang, S. H. Lin, and Y. T. Lee, Ab
initio/ RRKM approach toward
the understanding of ethylene photodissociation, J. Chem. Phys. 109, 2748(1998).
(IAMS)
(51) J. J. Lin, S. M. Wu, D. W. Hwang, and X. Yang, An excellent tool for
studying chemical reactions:
a new crossed molecular beam apparatus, Journal of Electronics (in Chinese)
36, 75(1998). (IAMS)
(52) J. J. Lin, D. W. Hwang, Y. T. Lee and X. Yang, Specific site and isotope
effects on the concerted
molecular hydrogen elimination from ethylene, J. Chem. Phys. 109, 2979(1998).
(JCP Communication)
(IAMS)
(53) J. J. Lin, Y. T. Lee and X. Yang, Crossed Molecular Beam Studies of
O(1D) + CH4: Evidences for
the CH2OH + H Channel, J. Chem. Phys. 109, 2975(1998). (JCP Communication)
(IAMS)
(54) D. Stranges, M. Stemmler, X. Yang, J. D. Chesko, A. G. Suits and Y.
T. Lee, UV photodissociation
dynamics of allyl radical by photofragment translational spectroscopy,
J. Chem. Phys. 109, 5372 (1998)
. (IAMS)
(55) J. J. Lin, S. M. Wu, D. W. Hwang, Y. T. Lee and X. Yang, Photodissociation
dynamics of
1,1-difluoroethylene at 157 nm excitation, J. Chem. Phys. 109, 10719(1998).
(IAMS)
(56) J. J. Lin, T. C. Hsu, D. W. Hwang, Y. T. Lee and X. Yang, Photodissociation
dynamics of
trifluoroethylene at 157 nm excitation, J. Chem. Phys. 109, 10838(1998).
(IAMS)
(57) D. W. Hwang, X. F. Yang, and X. Yang, Photodissociation of H2O: An
Excellent Case for
Unimolecular Dissociation, The Chinese Journal of Chemical Physics 11,
535(1999). (IAMS)
(58) D. W. Hwang, X. F. Yang, S. Harich, J. J. Lin and X. Yang, Photodissociation
dynamics of H2O at
121.6 nm: effect of parent rotational excitation on reaction pathways.
J. Chem. Phys. 110, 4123(1999)
(JCP Communication). (IAMS)
(59) D. W. Hwang, X. F. Yang, and X. Yang, The vibrational distribution
of the OH product from H2O
photodissociation at 157 nm: Discrepancies between theory and experiment.
J. Chem. Phys. 110, 4119
(1999) (JCP Communication). (IAMS)
(60) J. J. Lin, S. Harich, Y. T. Lee, and X. Yang, Dynamics of the O(1D)
+ CH4 reaction: atomic
hydrogen channel vs. molecular hydrogen channel, J. Chem. Phys. 110,
10821(1999). (IAMS)
(61) D. W. Hwang, J. J. Lin, S. M. Wu, and X. Yang, Hydrogen atom Rydberg
¨tagging〃 time-of-flight
technique: a powerful experimental method for studying chemical reactions,
Instruments Today
(in Chinese) 108, 7(1999). (IAMS)
(62) A. H. H. Chang, A. M. Mebel, D. W. Hwang, X. Yang, S. H. Lin, and
Y. T. Lee, Towards the
understanding of ethylene photodissociation: the calculations of Energy
partition in products and rate
constants, J. Chem. Phys. 110, 10810(1999). (IAMS)
(63) J. J. Lin, S. Harich, D. W. Hwang, S. M. Wu, Y. T. Lee and X. Yang,
Dynamics of atomic and
molecular elimination from hydrocarbons at VUV excitation, J. Chin. Chem.
Soc. 46, 435(1999).
(IAMS)
(64) S. Harich, J. J. Lin, Y. T. Lee and X. Yang, Competing Atomic and
Molecular Hydrogen Elimination
Processes from Photodissociation of Methanol at 157 nm, J. Chem. Phys.
111, 5(1999).
(JCP Communication). (IAMS)
(65) X. Liu, D. W. Huang, X. F. Yang, S. Harich, J. J. Lin, and X. Yang,
Photodissociation of H2S at
157 nm: Observation of SH Bimodal Rotational Distribution, J. Chem. Phys.
111, 3940(1999). (IAMS)
(66) S. M. Wu, J. J. Lin, Y. T. Lee, and X. Yang, Site Specificity on the
Molecular Hydrogen Elimination
from the photodissociation of propane at 157 nm, J. Chem. Phys. 111, 1793(1999).
(JCP Communication). (IAMS)
(67) R. N. Dixon, D. W. Huang, X. F. Yang, S. Harich, J. J. Lin, and X.
Yang, Chemical ¨Double Slits":
Dynamical Interference of Photodissociation Pathways of H2O, Science 285,
1249(1999). (IAMS)
(68) S. Harich, J. J. Lin, Y. T. Lee, and X. Yang, Photodissociation Dynamics
of Methanol at 157 nm,
J. Phys. Chem., in press. (IAMS)
(69) X. Liu, J. J. Lin, D. W. Hwang, X. F. Yang, and X. Yang, High Resolution
Translational Spectroscopic
Studies of Elementary Chemical Processes, Advances in Molecular Beam Research
and Applications,
Springer-Verlag, Editor R. Compargue (invited paper), in press. (IAMS)
(70) S. Harich, J. J. Lin, Y. T. Lee, and X. Yang, Site Specific Dissociation
Dynamics of Propyne at 157 nm
, J. Chem. Phys., in press. (IAMS)
(71) S. Harich, Y. T. Lee, and X. Yang, Photodissociation Dynamics of Allene
at 157 nm, Phys. Chem.
Chem. Phys., 2000, 2, 1187-1192. (IAMS)
(72) X. Liu, J. J. Lin, S. Harich, and X. Yang, Rotational State Resolved
Differential Cross Sections for
O(1D) + H2, ¨Imaging Techniques for Chemical Dynamics Research〃,
Proceedings of ACS
Meeting, New Orleans, August, 1999, in press. (IAMS)
(73) S. M. Wu, J. J. Lin, Y. T. Lee, and X. Yang, Photodissociation Dynamics
of Propane: Site Specificity
for Atomic and Molecular Hydrogen Elimination, J. Chem. Phys. 112, 8027(2000).
(IAMS)
(74) S. M. Wu, J. J. Lin, Y. T. Lee, and X. Yang, Photodissociation Dynamics
of Alkanes: Atomic and
Molecular Hydrogen Elimination Processes, J. Phys. Chem., accepted. (IAMS)
(75) J. J. Lin, Y. T. Lee, and X. Yang, Multiple Dynamical Pathways in
the O + SiH4 Reaction,
J. Chem. Phys., in press. (IAMS)
(76) X. F. Yang, D. W. Hwang, J. J. Lin and X. Yang, Dissociation Dynamics
of the Water Molecule on
the 1B1 Electronic Surface, J. Chem. Phys., in press. (IAMS)
(77) X. Liu, J. J. Lin, S. Harich, and X. Yang, Quantum State Specific
Dynamics for the
O(1D) + HD ? OD + H Reaction, J. Chem. Phys., accepted. (JCP Communication)
(IAMS)
(78) J. J. Lin, J. Shu, Y. T. Lee, and X. Yang, Multiple Dynamical Pathways
in the O(1D) + CH4
Reaction: A Comprehensive Crossed Beam Study, J. Chem. Phys., submitted.
(IAMS)
(79) J. Shu, J. J. Lin, Y. T. Lee, and X. Yang, Multiple Pathways in the
O(1D) + CH3F Reaction. (IAMS),
J. Chem. Phys., submitted. (IAMS)
(80) J. C. Wang, J. J. Lin, Y. T. Lee, and X. Yang, Photodissociation Dynamics
of Ethylene at 157 nm:
Atomic and Molecular Hydrogen Elimination, J. Chem. Phys. (IAMS), J. Chem.
Phys., in preparation.
(81) S. K. Gray, G. G. Balint-Kurti, G. C. Schatz, J. J. Lin, X. Liu, S.
Harich and X. Yang, Probing the
effect of the H2 rotational excitation in O(1D) + H2 ? OH + H: Theoretical
dynamics including
nonadiabatic effects and a crossed molecular beam study, J. Chem.
Phys., submitted.
(82) Xianghong Liu, Jim. J. Lin, Steven A. Harich, George C. Schatz and
Xueming Yang, A Benchmark
System for Insertion Chemistry: Quantum State Resolved Differential Cross
Sections for
O(1D) + H2 ? OH + H, submitted.