生化分子質譜與光譜學實驗室
Laboratory for Mass Spectrometric and Spectroscopic Studies of Biomolecules

Our research findings

The adiabatic ionization energy of di-substituted benzene derivatives has a "MOP" propensity.

"MOP" propensity: meta > ortho > para (MOP)

o-, m-, p-methylaniline
ionization energy:
m-methylaniline (61059 cm−1) > o-methylaniline (61002 cm−1) > p-methylaniline (60610 cm−1)

Mass analyzed threshold ionization spectroscopy of o-, m-, p-methylaniline cations: Vicinal substitution effects on electronic transition, ionization, and molecular vibration, J. L. Lin, K. C. Lin, and W. B. Tzeng, J. Phys. Chem. A 106, 6462–6468 (2002).

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背景音樂:給愛麗絲 (貝多芬)