生化分子質譜與光譜學實驗室
Laboratory for Mass Spectrometric and Spectroscopic Studies of Biomolecules

Our research findings

The adiabatic ionization energy of di-substituted benzene derivatives has a "MOP" propensity.

"MOP" propensity: meta > ortho > para (MOP)

o-, m-, p-fluoroanisole
ionization energy:
trans-m-fluoroanisole (68304 cm−1) > cis-m-fluoroanisole (67867 cm−1) > o-fluoroanisole (67354 cm−1) > p-fluoroanisole (66437 cm−1)

Rotamers of m-fluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy”,
Kui-Shiu Shiung, Dan Yu, Hsin-Chang Huang, and Wen Bih Tzeng,
J. Mol. Spectrosc. 274, 43–47 (2012)
Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization,
Kui Shiu Shiung, Dan Yu, Sheng Yuan Tzeng, and Wen Bih Tzeng,
Chem. Phys. Lett. 524, 3841 (2012)
 

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背景音樂:給愛麗絲 (貝多芬)