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(Left) Reaction path energetics for reactant
CHD3 initially in the £h = 0 (black arrow) and
£h1 = 1 (red) vibrational states. The curve
represents schematically a cut through the multidimensional potential energysurfaces
governing reactivity. The numbers in the
parentheses indicate the vibrational quanta
of the product pairs relevant to this study.
(Right)
Two normalized REMPI spectra of the probed CHD2 products, with IR-on (red) and IR-off (black), at Ec = 3.6 kcal/mol. Two product images, both with IR-on, are shown for probing of the Q and Q bands, respectively. Superimposed on the images are the scattering directions; the 0¢X angle refers to the initial CHD3 beam direction in the center-of-mass frame.

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  • Welcome new assistant research fellow Dr. Ming-Shien Chang. new!
  • Dr. Yuan Tseh Lee, along with Walter V. Reid, chair of the ICSU Earth System Visioning Task Group, and Catherine Bréchignac, president of ICSU, published an editorial entitled "Earth System Research Priorities" in Science on July 17, 2009.
  • Congratulations to Dr.Szu-yuan Chen on receiving 2009 NSC Ta-You Wu Memorial Award.
  • The research group led by Dr. Kopin Liu show that exciting the C¡VH stretching mode in the exothermic reaction F + CHD3 not only leads to unexpected products DF + CHD2 but also slows the reaction rate. Their results published in Science on July 17, 2009. This work has been highlighted on the C & EN (Chemical & Engineering News), Chemistry World, and Nature Chemistry website.
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2010 Annual Meeting of Asian CORE Program "Frontiers of Materials, Photo-, and Theoretical Molecular Sciences"
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